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Mercury has an exceptionally low melting temperature for a d-block metal

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Mercury has an exceptionally low melting temperature for a d-block metal Empty Mercury has an exceptionally low melting temperature for a d-block metal

Post by jancancook Mon Mar 28, 2011 9:40 am

Mercury has an exceptionally low melting temperature for a d-block metal. A complete explanation of this fact requires a deep excursion into quantum physics, but it can be summarized as follows: mercury has a unique electronic configuration where electrons fill up all the available 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f, 5s, 5p, 5d and 6s subshells. As such configuration strongly resists removal of an electron, mercury behaves similarly to noble gas elements, which form weak bonds and thus easily melting solids. The stability of the 6s shell is due to the presence of a filled 4f shell. An f shell poorly screens the nuclear charge that increases the attractive Coulomb interaction of the 6s shell and the nucleus (see lanthanide contraction). The absence of a filled inner f shell is the reason for the much higher melting temperature of cadmium. Metals such as gold have atoms with one less 6s electron than mercury. Those electrons are more easily removed and are shared between the gold atoms forming relatively strong metallic bonds.[3][5]

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jancancook
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